A lactone-fused cyclohexadiene as a versatile platform for diversified synthesis of 5,6,5-tricyclic scaffolds

A lactone-fused cyclohexadiene, which can be readily prepared by ruthenium(III)-catalyzed [2 + 2 + 2] cyclization of an enediyne, functioned as a versatile platform for the stereoselective synthesis of differently functionalized 5,6,5-tricyclic scaffolds.

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Veröffentlicht in:Organic & biomolecular chemistry 2015-06, Vol.13 (21), p.5862-5866
Hauptverfasser: Shibuya, M, Sudoh, T, Kawamura, T, Yamamoto, Y
Format: Artikel
Sprache:eng
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Zusammenfassung:A lactone-fused cyclohexadiene, which can be readily prepared by ruthenium(III)-catalyzed [2 + 2 + 2] cyclization of an enediyne, functioned as a versatile platform for the stereoselective synthesis of differently functionalized 5,6,5-tricyclic scaffolds.
ISSN:1477-0520
1477-0539
DOI:10.1039/c5ob00729a