Stereoselective synthesis of (2 R, 3 S)- syn-2-allyl-3-hydroxy butanoate mediated by an enzymatic system from bakers' yeast

Reduction of ethyl 2-allyl-3-oxobutanoate by an enzyme fraction obtained from bakers' yeast results in the formation of ethyl (2 R , 3 S )- syn -2-allyl-5-hydroxybutanoate in an excellent stereoselectivity. Graphic

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Tetrahedron letters 1990, Vol.31 (8), p.1159-1160
Hauptverfasser:	Nakamura, Kaoru, Miyai, Takehiko, Kawai, Yasushi, Nakajima, Nobuyoshi, Ohno, Atsuyoshi
Format:	Artikel
Sprache:	eng
Schlagworte:	3-hydroxybutyric acid Biological and medical sciences biosynthesis Fundamental and applied biological sciences. Psychology Mechanisms. Catalysis. Electron transfer. Models Molecular biophysics oxidoreductases Physical chemistry in biology Saccharomyces cerevisiae stereochemistry stereoisomers stereoselectivity
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Reduction of ethyl 2-allyl-3-oxobutanoate by an enzyme fraction obtained from bakers' yeast results in the formation of ethyl (2 R , 3 S )- syn -2-allyl-5-hydroxybutanoate in an excellent stereoselectivity. Graphic
ISSN:	0040-4039 1873-3581
DOI:	10.1016/S0040-4039(00)88752-3