All-solid-state sensors used in drilling muds to prevent H sub(2)S gas evolution on oil wells

During oil or water drilling, the evolution of gaseous hydrogen sulfide (H sub(2)S) may occur. A better solution would be to prevent the evolution of the gas by simultaneously measuring the presence of sulfide ions (S super(2)-) in the drilling mud and the pH, sulfide ions being predominantly under gaseous H sub(2)S form when pH is smaller than 7. We proposed then to perform in situ measurements, using a potentiometric technique, to simultaneously record the presence of sulfide and the pH of the mud. In case of a rapid decrease of pH, human action could be done to rapidly increase the pH and to prevent H sub(2)S evolution. A new type of all-solid-state reference electrode based on thick films of lithium lanthanum titanium oxide (LLTO) has therefore been developed. This reference electrode is associated with a solid state pH electrode and an ionic selective electrode for the detection of sulfide ions.