Is it possible to achieve a complete desaturation of cycloalkanes promoted by o-benzyne?

Is it possible to achieve a complete desaturation of cycloalkanes promoted by o-benzyne?

The competence between the possible reaction pathways in the reaction of different cycloalkanes and o-benzyne has been computationally explored. Systems able to undergo complete desaturation by consecutive double hydrogen atom transfer reactions are suggested.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-03, Vol.51 (25), p.5302-5305
Hauptverfasser: Cervantes-Navarro, Francisco, de Cózar, Abel, Cossío, Fernando P, Fernández-Herrera, María A, Merino, Gabriel, Fernández, Israel
Format: Artikel
Sprache:eng
Schlagworte:
Computation
Cycloalkanes
Desaturation
Hydrogen atoms
Pathways
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Beschreibung
Zusammenfassung:The competence between the possible reaction pathways in the reaction of different cycloalkanes and o-benzyne has been computationally explored. Systems able to undergo complete desaturation by consecutive double hydrogen atom transfer reactions are suggested.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc07311h