Reversible crystal deformation of a single-crystal host of copper(II) 1-naphthoate-pyrazine through crystal phase transition induced by methanol vapor sorption

Reversible crystal deformation of a single-crystal host of copper(II) 1-naphthoate-pyrazine through crystal phase transition induced by methanol vapor sorption

A novel microporous single crystal of [Cu(II)2(1-NA)4(pyz)]n (1-NA: 1-naphthoate, pyz: pyrazine) exhibited bending and straightening action on a macroscopic scale during the first-order crystal phase transition induced by methanol vapor sorption.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (24), p.5024-5027
Hauptverfasser: Takasaki, Yuichi, Takamizawa, Satoshi
Format: Artikel
Sprache:eng
Schlagworte:
Adsorption
Bending
Carboxylic Acids - chemistry
Copper - chemistry
Crystallization
Crystals
Methanol - chemistry
Methyl alcohol
Naphthalenes - chemistry
Organometallic Compounds - chemistry
Particle Size
Phase transformations
Phase Transition
Porosity
Pyrazines
Pyrazines - chemistry
Single crystals
Sorption
Straightening
Surface Properties
Volatilization
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Zusammenfassung:A novel microporous single crystal of [Cu(II)2(1-NA)4(pyz)]n (1-NA: 1-naphthoate, pyz: pyrazine) exhibited bending and straightening action on a macroscopic scale during the first-order crystal phase transition induced by methanol vapor sorption.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc09948f