Precision Polymers through ADMET Polymerization

Acyclic diene metathesis (ADMET) polymerization is a unique strategy for achieving polymers with precise control over the primary structure. This precision is obtained by specific monomer design and carefully controlled polymerization conditions. Over time, this approach has produced an array of sop...

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Veröffentlicht in:	Macromolecular chemistry and physics 2014-10, Vol.215 (20), p.1936-1945
Hauptverfasser:	Schulz, Michael D., Wagener, Kenneth B.
Format:	Artikel
Sprache:	eng
Schlagworte:	ADMET polymerization Arrays Decomposition reactions Dienes Grubbs catalyst Metathesis Monomers olefin metathesis Polyethylenes Polymerization Polymers precision polymers Rotaxanes Strategy
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Zusammenfassung:	Acyclic diene metathesis (ADMET) polymerization is a unique strategy for achieving polymers with precise control over the primary structure. This precision is obtained by specific monomer design and carefully controlled polymerization conditions. Over time, this approach has produced an array of sophisticated architectures ranging from precise polyethylenes, to hyperbranched polymers, to rotaxanes. Acyclic diene metathesis (ADMET) polymerization is a powerful tool for creating precision polymers. This review summarizes the use of ADMET polymerization to synthesize precision polyethylene model compounds and various advanced polymer structures.
ISSN:	1022-1352 1521-3935
DOI:	10.1002/macp.201400268