Mirror symmetry breaking upon spontaneous crystallization from a dynamic combinatorial library of macrocyclic imines

Mirror symmetry breaking upon spontaneous crystallization from a dynamic combinatorial library of macrocyclic imines

Spontaneous emergence of solid state chirality and mirror symmetry breaking occurred upon crystallization from a small templated dynamic combinatorial library (DCL) of achiral macrocyclic imines, and depended strongly on the nature of library building blocks (amines, aldehydes, template cations and...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-03, Vol.51 (20), p.4306-4309
Hauptverfasser: Ziach, Krzysztof, Jurczak, Janusz
Format: Artikel
Sprache:eng
Schlagworte:
Broken symmetry
Cations
Combinatorial analysis
Crystallization
Dynamics
Imines
Libraries
Macrocyclic compounds
Spontaneous
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Beschreibung
Zusammenfassung:Spontaneous emergence of solid state chirality and mirror symmetry breaking occurred upon crystallization from a small templated dynamic combinatorial library (DCL) of achiral macrocyclic imines, and depended strongly on the nature of library building blocks (amines, aldehydes, template cations and anions) and crystallization temperature.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc10083b