Recent Trends in the Chemistry of Shape-Memory Polymers

Shape‐memory polymers (SMPs) are stimuli‐sensitive materials capable of performing complex movements on demand, which makes them interesting candidates for various applications, for example, in biomedicine or aerospace. This trend article highlights current approaches in the chemistry of SMPs, such as tailored segment chemistry to integrate additional functions and novel synthetic routes toward permanent and temporary netpoints. Multiphase polymer networks and multimaterial systems illustrate that SMPs can be constructed as a modular system of different building blocks and netpoints. Future developments are aiming at multifunctional and multistimuli‐sensitive SMPs. Shape‐memory polymers (SMPs) are stimuli‐sensitive materials capable of performing complex movements on demand. This trend article highlights current approaches in the chemistry of SMPs (e.g., tailoring segment chemistry to integrate additional functions). It is illustrated that SMPs can be constructed on the molecular level as a modular system of different building blocks and netpoints.