Highly hydrated Nafion/activated carbon hybrids

The incorporation of highly porous activated carbon (aC) to Nafion membranes confers unprecedented levels of water uptake (4 times higher for 10 wt% aC compared to neat Nafion) at a minimal dimensional swelling and results in dramatic enhancements in ionic conductivity at low relative humidity. This...

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Veröffentlicht in:Polymer (Guilford) 2012-10, Vol.53 (22), p.4927-4930
Hauptverfasser: Chien, Hung-Chung, Tsai, Li-Duan, Kelarakis, Antonios, Lai, Chien-Ming, Lin, Jiunn-Nan, Fang, Jason, Zhu, Chao-Yuan, Chang, Feng-Chih
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Sprache:eng
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Zusammenfassung:The incorporation of highly porous activated carbon (aC) to Nafion membranes confers unprecedented levels of water uptake (4 times higher for 10 wt% aC compared to neat Nafion) at a minimal dimensional swelling and results in dramatic enhancements in ionic conductivity at low relative humidity. This behavior reveals the development of a robust network of water nanochannels formed by the carbon pores and the polymeric ionic domains which are structurally stabilized by the rigid Nafion backbone and the non-deformable aC particles. [Display omitted]
ISSN:0032-3861
1873-2291
DOI:10.1016/j.polymer.2012.08.061