Highly hydrated Nafion/activated carbon hybrids
The incorporation of highly porous activated carbon (aC) to Nafion membranes confers unprecedented levels of water uptake (4 times higher for 10 wt% aC compared to neat Nafion) at a minimal dimensional swelling and results in dramatic enhancements in ionic conductivity at low relative humidity. This...
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Veröffentlicht in: | Polymer (Guilford) 2012-10, Vol.53 (22), p.4927-4930 |
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Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The incorporation of highly porous activated carbon (aC) to Nafion membranes confers unprecedented levels of water uptake (4 times higher for 10 wt% aC compared to neat Nafion) at a minimal dimensional swelling and results in dramatic enhancements in ionic conductivity at low relative humidity. This behavior reveals the development of a robust network of water nanochannels formed by the carbon pores and the polymeric ionic domains which are structurally stabilized by the rigid Nafion backbone and the non-deformable aC particles.
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ISSN: | 0032-3861 1873-2291 |
DOI: | 10.1016/j.polymer.2012.08.061 |