Bio-inspired beehive-like hierarchical nanoporous carbon derived from bamboo-based industrial by-product as a high performance supercapacitor electrode material

Bio-inspired beehive-like hierarchical nanoporous carbon (BHNC) with a high specific surface area of 1472 m 2 g −1 and a good electronic conductivity of 4.5 S cm −1 is synthesized by carbonizing the industrial waste of bamboo-based by-product. The BHNC sample exhibits remarkable electrochemical perf...

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Veröffentlicht in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2015-01, Vol.3 (10), p.5656-5664
Hauptverfasser: Tian, Weiqian, Gao, Qiuming, Tan, Yanli, Yang, Kai, Zhu, Lihua, Yang, Chunxiao, Zhang, Hang
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Sprache:eng
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Zusammenfassung:Bio-inspired beehive-like hierarchical nanoporous carbon (BHNC) with a high specific surface area of 1472 m 2 g −1 and a good electronic conductivity of 4.5 S cm −1 is synthesized by carbonizing the industrial waste of bamboo-based by-product. The BHNC sample exhibits remarkable electrochemical performances as a supercapacitor electrode material, such as a high specific capacitance of 301 F g −1 at 0.1 A g −1 , still maintaining a value of 192 F g −1 at 100 A g −1 , negligible capacitance loss after 20 000 cycles at 1 A g −1 , and a high power density of 26 000 W kg −1 at an energy density of 6.1 W h kg −1 based on active electrode materials in an aqueous electrolyte system. Moreover, an enhanced power density of 42 000 W kg −1 at a high energy density of 43.3 W h kg −1 is obtained in an ionic liquid electrolyte system, which places the BHNC-based supercapacitors in the Ragone chart among the best energy–power synergetic outputting properties ever reported for carbon-based supercapacitors.
ISSN:2050-7488
2050-7496
DOI:10.1039/C4TA06620K