Bio-inspired beehive-like hierarchical nanoporous carbon derived from bamboo-based industrial by-product as a high performance supercapacitor electrode material
Bio-inspired beehive-like hierarchical nanoporous carbon (BHNC) with a high specific surface area of 1472 m 2 g −1 and a good electronic conductivity of 4.5 S cm −1 is synthesized by carbonizing the industrial waste of bamboo-based by-product. The BHNC sample exhibits remarkable electrochemical perf...
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Veröffentlicht in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2015-01, Vol.3 (10), p.5656-5664 |
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Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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Zusammenfassung: | Bio-inspired beehive-like hierarchical nanoporous carbon (BHNC) with a high specific surface area of 1472 m
2
g
−1
and a good electronic conductivity of 4.5 S cm
−1
is synthesized by carbonizing the industrial waste of bamboo-based by-product. The BHNC sample exhibits remarkable electrochemical performances as a supercapacitor electrode material, such as a high specific capacitance of 301 F g
−1
at 0.1 A g
−1
, still maintaining a value of 192 F g
−1
at 100 A g
−1
, negligible capacitance loss after 20 000 cycles at 1 A g
−1
, and a high power density of 26 000 W kg
−1
at an energy density of 6.1 W h kg
−1
based on active electrode materials in an aqueous electrolyte system. Moreover, an enhanced power density of 42 000 W kg
−1
at a high energy density of 43.3 W h kg
−1
is obtained in an ionic liquid electrolyte system, which places the BHNC-based supercapacitors in the Ragone chart among the best energy–power synergetic outputting properties ever reported for carbon-based supercapacitors. |
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ISSN: | 2050-7488 2050-7496 |
DOI: | 10.1039/C4TA06620K |