Carbon Dioxide Splitting in a Dielectric Barrier Discharge Plasma: A Combined Experimental and Computational Study

Plasma technology is gaining increasing interest for the splitting of CO2 into CO and O2. We have performed experiments to study this process in a dielectric barrier discharge (DBD) plasma with a wide range of parameters. The frequency and dielectric material did not affect the CO2 conversion and energy efficiency, but the discharge gap can have a considerable effect. The specific energy input has the most important effect on the CO2 conversion and energy efficiency. We have also presented a plasma chemistry model for CO2 splitting, which shows reasonable agreement with the experimental conversion and energy efficiency. This model is used to elucidate the critical reactions that are mostly responsible for the CO2 conversion. Finally, we have compared our results with other CO2 splitting techniques and we identified the limitations as well as the benefits and future possibilities in terms of modifications of DBD plasmas for greenhouse gas conversion in general. Split it: Plasma technology is gaining increasing interest for the splitting of CO2 into CO and O2. However, only some scattered results on pure CO2 splitting have been reported. We present an in‐depth study of the conversion and energy efficiency of CO2 splitting by using a dielectric barrier discharge plasma in a wide range of applied frequencies, electric powers, and gas flow rates and by combining experimental and computational results.