Preparation of PVDF/CaCO sub(3) composite hollow fiber membrane via a thermally induced phase separation method

The spinnabiliy of polyvinylidene fluoride (PVDF)/CaCO sub(3) microparticle dope solution were explored via a thermally induced phase separation process, and composite hollow fiber (CHF) membranes were prepared successfully. The experiment results showed that the self-supporting property of CHF got improved after adding CaCO sub(3) at low concentration of PVDF, so the control of spinning process became easy. The effects of CaCO sub(3) on the structure and properties of hollow fiber membrane were investigated in terms of morphology, water flux, porosity, breakage strength, and crystallization. The results indicated that CHF presented a uniform bicontinuous structure. The permeability and porosity of CHF increased obviously when CaCO sub(3) was removed by acid, while the breakage strength decreased slightly. CHF presented a good drying stability. POLYM. COMPOS., 34:1204-1210, 2013. copyright 2013 Society of Plastics Engineers