Rhodium(III)-Catalyzed Annulation of Azomethine Ylides with Alkynes via CH Activation

The rhodium(III)‐catalyzed coupling of azomethine ylides with alkynes via CH activation has been developed for the synthesis of indenamines in moderate to high yields. The coupled products can be further oxidized to indenones and derivatives.

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Veröffentlicht in:	Advanced synthesis & catalysis 2013-02, Vol.355 (2-3), p.353-359
Hauptverfasser:	Chen, Yuye, Wang, Fen, Zhen, Wencui, Li, Xingwei
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Alkynes Catalysis Chemical reactions cyclization CH activation Derivatives indenamines Joining Organic chemistry rhodium Synthesis
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creator	Chen, Yuye Wang, Fen Zhen, Wencui Li, Xingwei
description	The rhodium(III)‐catalyzed coupling of azomethine ylides with alkynes via CH activation has been developed for the synthesis of indenamines in moderate to high yields. The coupled products can be further oxidized to indenones and derivatives.
doi_str_mv	10.1002/adsc.201200924
format	Article
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subjects	Activation Alkynes Catalysis Chemical reactions cyclization CH activation Derivatives indenamines Joining Organic chemistry rhodium Synthesis
title	Rhodium(III)-Catalyzed Annulation of Azomethine Ylides with Alkynes via CH Activation
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