Rhodium(III)-Catalyzed Annulation of Azomethine Ylides with Alkynes via CH Activation

Rhodium(III)-Catalyzed Annulation of Azomethine Ylides with Alkynes via CH Activation

The rhodium(III)‐catalyzed coupling of azomethine ylides with alkynes via CH activation has been developed for the synthesis of indenamines in moderate to high yields. The coupled products can be further oxidized to indenones and derivatives.

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Veröffentlicht in:Advanced synthesis & catalysis 2013-02, Vol.355 (2-3), p.353-359
Hauptverfasser: Chen, Yuye, Wang, Fen, Zhen, Wencui, Li, Xingwei
Format: Artikel
Sprache:eng
Schlagworte:
Activation
Alkynes
Catalysis
Chemical reactions
cyclization
CH activation
Derivatives
indenamines
Joining
Organic chemistry
rhodium
Synthesis
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Beschreibung
Zusammenfassung:The rhodium(III)‐catalyzed coupling of azomethine ylides with alkynes via CH activation has been developed for the synthesis of indenamines in moderate to high yields. The coupled products can be further oxidized to indenones and derivatives.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201200924