Porphyrin-based Coordination Polymer Composed of Layered Pillarless Two-dimensional Networks
Single crystals of a layer-structured coordination polymer, BNAS-11 [ZnTCPP(H2O)Zn2(H2O)2] (ZnTCPP: 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinatozinc(II)), were obtained. Tetratopic ZnTCPP molecules are connected through dimer zinc paddle-wheel secondary building units and form a two-dimensional...
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Veröffentlicht in: | Chemistry letters 2014-07, Vol.43 (7), p.1161-1163 |
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creator | Makiura, Rie Usui, Ryo Pohl, Ehmke Prassides, Kosmas |
description | Single crystals of a layer-structured coordination polymer, BNAS-11 [ZnTCPP(H2O)Zn2(H2O)2] (ZnTCPP: 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinatozinc(II)), were obtained. Tetratopic ZnTCPP molecules are connected through dimer zinc paddle-wheel secondary building units and form a two-dimensional (2D) network with square grids. The layers are stacked electrostatically without the need of binding pillar ligands. |
doi_str_mv | 10.1246/cl.140275 |
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Tetratopic ZnTCPP molecules are connected through dimer zinc paddle-wheel secondary building units and form a two-dimensional (2D) network with square grids. 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Tetratopic ZnTCPP molecules are connected through dimer zinc paddle-wheel secondary building units and form a two-dimensional (2D) network with square grids. The layers are stacked electrostatically without the need of binding pillar ligands.</description><subject>Binding</subject><subject>Construction</subject><subject>Coordination polymers</subject><subject>Coordination Programming</subject><subject>Dimers</subject><subject>Ligands</subject><subject>Networks</subject><subject>Two dimensional</subject><subject>Zinc</subject><issn>0366-7022</issn><issn>1348-0715</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNplkEtLw0AUhQdRsFYX_oOAG12kziszk6UUX1C0i7oTwmRyQ6cmmTiTUvLvndIuRFf3cu93DoeD0DXBM0K5uDfNjHBMZXaCJoRxlWJJslM0wUyIVGJKz9FFCBuMscoZnaDPpfP9evS2S0sdoErmzvnKdnqwrkuWrhlb8PHY9m7_dXWy0CP4uC5t02jfQAjJaufSyrbQhSjSTfIGw875r3CJzmrdBLg6zin6eHpczV_Sxfvz6_xhkZoM0yGFvMy00EZWsq6YUoZpKgwzChg3kjBGhBYlh1yqMlMAtRKYi1qYugSc55xN0e3Bt_fuewthKFobDMR8HbhtKIiQRGAscxHRmz_oxm19DB2pjDPCFc9ppO4OlPEuBA910Xvbaj8WBBf7ngvTFIeeIyuO7Bpaa6KTMxaGcaN73f1y_yf8AbKkg4M</recordid><startdate>20140705</startdate><enddate>20140705</enddate><creator>Makiura, Rie</creator><creator>Usui, Ryo</creator><creator>Pohl, Ehmke</creator><creator>Prassides, Kosmas</creator><general>The Chemical Society of Japan</general><general>Chemical Society of Japan</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20140705</creationdate><title>Porphyrin-based Coordination Polymer Composed of Layered Pillarless Two-dimensional Networks</title><author>Makiura, Rie ; Usui, Ryo ; Pohl, Ehmke ; Prassides, Kosmas</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c502t-e9b5a6ac7d7fd388c3a26c3c8e34c713316a6b4e978b58eef86046f6cfbe09943</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Binding</topic><topic>Construction</topic><topic>Coordination polymers</topic><topic>Coordination Programming</topic><topic>Dimers</topic><topic>Ligands</topic><topic>Networks</topic><topic>Two dimensional</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Makiura, Rie</creatorcontrib><creatorcontrib>Usui, Ryo</creatorcontrib><creatorcontrib>Pohl, Ehmke</creatorcontrib><creatorcontrib>Prassides, Kosmas</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Makiura, Rie</au><au>Usui, Ryo</au><au>Pohl, Ehmke</au><au>Prassides, Kosmas</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Porphyrin-based Coordination Polymer Composed of Layered Pillarless Two-dimensional Networks</atitle><jtitle>Chemistry letters</jtitle><addtitle>Chemistry Letters</addtitle><date>2014-07-05</date><risdate>2014</risdate><volume>43</volume><issue>7</issue><spage>1161</spage><epage>1163</epage><pages>1161-1163</pages><issn>0366-7022</issn><eissn>1348-0715</eissn><abstract>Single crystals of a layer-structured coordination polymer, BNAS-11 [ZnTCPP(H2O)Zn2(H2O)2] (ZnTCPP: 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinatozinc(II)), were obtained. 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source | Oxford University Press Journals All Titles (1996-Current) |
subjects | Binding Construction Coordination polymers Coordination Programming Dimers Ligands Networks Two dimensional Zinc |
title | Porphyrin-based Coordination Polymer Composed of Layered Pillarless Two-dimensional Networks |
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