Porphyrin-based Coordination Polymer Composed of Layered Pillarless Two-dimensional Networks

Porphyrin-based Coordination Polymer Composed of Layered Pillarless Two-dimensional Networks

Single crystals of a layer-structured coordination polymer, BNAS-11 [ZnTCPP(H2O)Zn2(H2O)2] (ZnTCPP: 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinatozinc(II)), were obtained. Tetratopic ZnTCPP molecules are connected through dimer zinc paddle-wheel secondary building units and form a two-dimensional...

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Veröffentlicht in:Chemistry letters 2014-07, Vol.43 (7), p.1161-1163
Hauptverfasser: Makiura, Rie, Usui, Ryo, Pohl, Ehmke, Prassides, Kosmas
Format: Artikel
Sprache:eng
Schlagworte:
Binding
Construction
Coordination polymers
Coordination Programming
Dimers
Ligands
Networks
Two dimensional
Zinc
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Zusammenfassung:Single crystals of a layer-structured coordination polymer, BNAS-11 [ZnTCPP(H2O)Zn2(H2O)2] (ZnTCPP: 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinatozinc(II)), were obtained. Tetratopic ZnTCPP molecules are connected through dimer zinc paddle-wheel secondary building units and form a two-dimensional (2D) network with square grids. The layers are stacked electrostatically without the need of binding pillar ligands.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.140275