Experimental validation of a lumped model of single droplet deformation, oscillation and detachment on the GDL surface of a PEM fuel cell

Proton Exchange Membrane Fuel Cell (PEMFC) performance significantly depends on electrodes water content. Liquid water emerging from the Gas Diffusion Layer (GDL) micro-channels can form droplets, films or slugs in the Gas Flow Channel (GFC). In the regime of droplets formation, the interaction with...

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Veröffentlicht in:International journal of hydrogen energy 2013-07, Vol.38 (21), p.8934-8953
Hauptverfasser: Polverino, Pierpaolo, Esposito, Angelo, Pianese, Cesare
Format: Artikel
Sprache:eng
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Zusammenfassung:Proton Exchange Membrane Fuel Cell (PEMFC) performance significantly depends on electrodes water content. Liquid water emerging from the Gas Diffusion Layer (GDL) micro-channels can form droplets, films or slugs in the Gas Flow Channel (GFC). In the regime of droplets formation, the interaction with the gas flow leads to an oscillating mechanisms that is fundamental to study the detachment from the GDL surface. In this work, a numerical model of a droplet growing on the GDL surface is developed to describe the interaction between droplet and gas flow. Therefore, a lumped force balance is enforced to determine the center of mass motion law. Oscillation frequencies during growth and at detachment are found as a function of droplet size. The model is also exploited to find the relationship between droplet critical detachment size and gas velocity. The numerical results are compared with the experimental data previously published by the authors as well as with other experimental results available in the literature. The matching between the numerical and experimental data is very good. The low computational burden and the conciseness of the proposed approach make the model suitable for applications such as control and optimization strategies development to enhance PEMFC performance. Additionally, the model can be exploited to implement monitoring and diagnostic algorithm as well. •Water droplet oscillation and detachment due to air flow has been investigated through a dynamic model.•A simplified geometric representation has been exploited for a dynamic force balance.•Droplet oscillation has been found to be crucial for droplet detachment.•Simulation results are in good agreement with the experimental ones.•The model is fast and reliable for PEMFC optimal design, control and diagnostic studies.
ISSN:0360-3199
1879-3487
DOI:10.1016/j.ijhydene.2013.04.143