Black brookite titania with high solar absorption and excellent photocatalytic performance

Black platelike brookite with outstanding photocatalytic performance is prepared by constructing a distinct crystalline core/disordered shell structure (TiO sub(2)[at]TiO sub(2-x)) through aluminium reduction. Many oxygen vacancies and Ti super(3+) states are introduced into the distorted shell, whi...

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Veröffentlicht in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2013-08, Vol.1 (34), p.9650-9653
Hauptverfasser: Zhu, Guilian, Lin, Tianquan, Lue, Xujie, Zhao, Wei, Yang, Chongyin, Wang, Zhou, Yin, Hao, Liu, Zhanqiang, Huang, Fuqiang, Lin, Jianhua
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Sprache:eng
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Zusammenfassung:Black platelike brookite with outstanding photocatalytic performance is prepared by constructing a distinct crystalline core/disordered shell structure (TiO sub(2)[at]TiO sub(2-x)) through aluminium reduction. Many oxygen vacancies and Ti super(3+) states are introduced into the distorted shell, which increase the solar energy absorption and boost the photocatalytic activity.
ISSN:2050-7488
2050-7496
DOI:10.1039/c3ta11782k