Proton switch for modulating oxygen reduction by a copper electrocatalyst embedded in a hybrid bilayer membrane

Molecular switches gate many fundamental processes in natural and artificial systems. Here, we report the development of an electrochemical platform in which a proton carrier switches the activity of a catalyst. By incorporating an alkyl phosphate in the lipid layer of a hybrid bilayer membrane, we...

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Veröffentlicht in:Nature materials 2014-06, Vol.13 (6), p.619-623
Hauptverfasser: Barile, Christopher J., Tse, Edmund C. M., Li, Ying, Sobyra, Thomas B., Zimmerman, Steven C., Hosseini, Ali, Gewirth, Andrew A.
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Sprache:eng
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