Synthesis and characterization of macroporous Ni, Co and Ni–Co electrocatalytic deposits for hydrogen evolution reaction in alkaline media

In this work, macroporous Ni, Co and Ni–Co electrodes have been developed by co-deposition at high current density on stainless steel (AISI 304) substrates. The obtained materials were characterized both morphologically and chemically by confocal laser scanning microscopy, and SEM coupled with EDX analysis. The activity for hydrogen evolution reaction (HER) on the obtained layers was assessed by using pseudo-steady-state polarization curves and electrochemical impedance spectroscopy (EIS) in alkaline solution (30 wt.% KOH). The electrochemical results show that HER on these electrodes takes place by the Volmer–Heyrovsky mechanism. The synthesized coatings present higher catalytic activity for HER than commercial smooth Ni electrode. As the Co content increases in the electrodeposition bath the obtained structures show lower surface roughness factors. Ni–Co deposit with a Co content of 43 at.% manifests the highest intrinsic activity for HER as a consequence of the synergetic combination of Ni and Co. •Macroporous Ni and NiCo electrodes have been developed.•Electrodes were synthesized at high current density on AISI 304 stainless steel.•NiCo deposit with a Co content of 43 at.% manifests the highest intrinsic activity.•The HER on the developed electrodes is controlled by the Volmer–Heyrovsky mechanism.