Solvent-Induced Delamination of a Multifunctional Two Dimensional Coordination Polymer

A coordination polymer is fully exfoliated by solvent‐assisted interaction only. The soft‐delamination process results from the structure of the starting material, which shows a layered structure with weak layer‐to‐layer interactions and cavities with the ability to locate several solvents in an uns...

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Veröffentlicht in:Advanced materials (Weinheim) 2013-04, Vol.25 (15), p.2141-2146
Hauptverfasser: Gallego, Almudena, Hermosa, Cristina, Castillo, Oscar, Berlanga, Isadora, Gómez-García, Carlos J., Mateo-Martí, Eva, Martínez, José I., Flores, Fernando, Gómez-Navarro, Cristina, Gómez-Herrero, Julio, Delgado, Salome, Zamora, Félix
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container_end_page 2146
container_issue 15
container_start_page 2141
container_title Advanced materials (Weinheim)
container_volume 25
creator Gallego, Almudena
Hermosa, Cristina
Castillo, Oscar
Berlanga, Isadora
Gómez-García, Carlos J.
Mateo-Martí, Eva
Martínez, José I.
Flores, Fernando
Gómez-Navarro, Cristina
Gómez-Herrero, Julio
Delgado, Salome
Zamora, Félix
description A coordination polymer is fully exfoliated by solvent‐assisted interaction only. The soft‐delamination process results from the structure of the starting material, which shows a layered structure with weak layer‐to‐layer interactions and cavities with the ability to locate several solvents in an unselective way. These results represent a significant step forward towards the production of structurally designed one‐molecule thick 2D materials with tailored physico‐chemical properties.
doi_str_mv 10.1002/adma.201204676
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source Wiley Online Library Journals Frontfile Complete
subjects 2D materials
Coordination polymers
crystal-to-crystal transformation
Delaminating
Delamination
Exfoliation
Holes
MOF on surfaces
MOFs
multifunctional materials
Solvents
Two dimensional
title Solvent-Induced Delamination of a Multifunctional Two Dimensional Coordination Polymer
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