Solvent-Induced Delamination of a Multifunctional Two Dimensional Coordination Polymer

Solvent-Induced Delamination of a Multifunctional Two Dimensional Coordination Polymer

A coordination polymer is fully exfoliated by solvent‐assisted interaction only. The soft‐delamination process results from the structure of the starting material, which shows a layered structure with weak layer‐to‐layer interactions and cavities with the ability to locate several solvents in an uns...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Weinheim) 2013-04, Vol.25 (15), p.2141-2146
Hauptverfasser: Gallego, Almudena, Hermosa, Cristina, Castillo, Oscar, Berlanga, Isadora, Gómez-García, Carlos J., Mateo-Martí, Eva, Martínez, José I., Flores, Fernando, Gómez-Navarro, Cristina, Gómez-Herrero, Julio, Delgado, Salome, Zamora, Félix
Format: Artikel
Sprache:eng
Schlagworte:
2D materials
Coordination polymers
crystal-to-crystal transformation
Delaminating
Delamination
Exfoliation
Holes
MOF on surfaces
MOFs
multifunctional materials
Solvents
Two dimensional
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A coordination polymer is fully exfoliated by solvent‐assisted interaction only. The soft‐delamination process results from the structure of the starting material, which shows a layered structure with weak layer‐to‐layer interactions and cavities with the ability to locate several solvents in an unselective way. These results represent a significant step forward towards the production of structurally designed one‐molecule thick 2D materials with tailored physico‐chemical properties.
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.201204676