A hybrid polyoxometalate-organic molecular catalyst for visible light driven water oxidation

A hybrid polyoxometalate-organic molecular catalyst for visible light driven water oxidation

A novel organic-inorganic hybrid monocapped/bicapped Keggin structure [Co(II)(bpy)3]6(H2bpy)[(Co(II)bpy)2(PMo8(VI)Mo4(V)O40)]3 [(Co(II)bpy)(PMo8(VI)Mo4(V)O40)]·16H2O (bpy = 2,2'-bipyridine) was synthesized and shown to be an efficient visible light-driven catalyst for water oxidation.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-10, Vol.50 (78), p.11591-11594
Hauptverfasser: Zhang, C, Lin, X, Zhang, Z, Long, L-S, Wang, C, Lin, W
Format: Artikel
Sprache:eng
Schlagworte:
Catalysts
Molecular structure
Oxidation
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Zusammenfassung:A novel organic-inorganic hybrid monocapped/bicapped Keggin structure [Co(II)(bpy)3]6(H2bpy)[(Co(II)bpy)2(PMo8(VI)Mo4(V)O40)]3 [(Co(II)bpy)(PMo8(VI)Mo4(V)O40)]·16H2O (bpy = 2,2'-bipyridine) was synthesized and shown to be an efficient visible light-driven catalyst for water oxidation.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc03487b