Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution

It is important to know how ILs（ionic liquids） influence organic reaction. In this paper, activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically. Through the study on typical organic reactions happened in ILs, such as Diels-Alder...

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Veröffentlicht in:	Chinese journal of chemical engineering 2013-12, Vol.21 (12), p.1370-1375
1. Verfasser:	马征董晓霞胡玉峰张柏松徐长英刘艳升
Format:	Artikel
Sprache:	eng
Schlagworte:	Activity coefficients activity coefficients at infinite dilution Chemical engineering Esterification Estimates Friedel-Crafts reaction Friedel-Crafts反应 ionic liquid Ionic liquids Organic compounds organic reactions Selectivity 无限稀释有机化合物有机反应活度系数离子液体选择性反应酯化反应
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Beschreibung
Zusammenfassung:	It is important to know how ILs（ionic liquids） influence organic reaction. In this paper, activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically. Through the study on typical organic reactions happened in ILs, such as Diels-Alder, esterification and Friedel-Crafts reaction, the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.
ISSN:	1004-9541 2210-321X
DOI:	10.1016/S1004-9541(13)60640-0