Hydrophilic gold nanoparticles stabilized with tris(2-aminoethyl)amine: Preparation and characterization

•The synthesis of Au NPs stabilized with of tris(2-aminoethyl)amine is presented.•Final product is powder of Au NPs with protective shells.•Shells compose of the adducts of tris(2-aminoethyl)amine, acetone and boric acid.•The composition of powder is Au{N(CH2CH2NH2)3}36{OC(CH3)2}36{H3BO3}32{NaBO2}4{...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Colloids and surfaces. A, Physicochemical and engineering aspects Physicochemical and engineering aspects, 2014-01, Vol.441, p.496-503
Hauptverfasser: Tatarchuk, Vladimir V., Sergievskaya, Anastasiya P., Zaikovsky, Vladimir I., Gevko, Pavel N., Gallyamov, Marsel R., Plusnin, Pavel E., Popovezky, Pavel S., Antonova, Olga V.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:•The synthesis of Au NPs stabilized with of tris(2-aminoethyl)amine is presented.•Final product is powder of Au NPs with protective shells.•Shells compose of the adducts of tris(2-aminoethyl)amine, acetone and boric acid.•The composition of powder is Au{N(CH2CH2NH2)3}36{OC(CH3)2}36{H3BO3}32{NaBO2}4{NaCl}4.•Powder of Au NPs is hydrophilic and redisperse in water and polar solvents. The synthesis of Au nanoparticles through the reduction of HAuCl4 with sodium borohydride in a mixture of ethanol and isopropanol in the presence of tris(2-aminoethyl)amine is presented. The resulting powder preparation is a mixture of primary particles with the average diameter of golden cores 3.2±0.6nm, and secondary particles that were formed as a result of agglomeration of the primary ones and have core diameter up to 20nm. The Au content of the preparation is 1.94% because Au nanoparticles have voluminous protective shells composed of the adducts of tris(2-aminoethyl)amine, acetone and boric acid, formed due to hydrogen bonding. The preparation is hydrophilic and allows one to obtain colloid solutions in water and polar solvents like acetone, isopropanol, dimethylsulphoxide, and in chloroform under ultrasonic treatment.
ISSN:0927-7757
1873-4359
DOI:10.1016/j.colsurfa.2013.10.015