Iodide-promoted Deselenylation of [beta]-Chloro- and [beta]-Oxyselenides to Form Alkenes and Selenenyl Iodides

Iodide-promoted Deselenylation of [beta]-Chloro- and [beta]-Oxyselenides to Form Alkenes and Selenenyl Iodides

Deselenylation reaction of [beta]-chloro- and [beta]-oxyselenides proceeded efficiently by treatment with tetrabutylammonium iodide (TBAI) to afford alkenes in good yields. It was established that selenenyl iodides were formed in these reactions. Catalytic transformation of [beta]-chloro- and [beta]...

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Veröffentlicht in:Chemistry letters 2012-01, Vol.41 (8), p.766-768
Hauptverfasser: Sase, Shohei, Ebisawa, Kazuaki, Goto, Kei
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes
Catalysis
Catalysts
Iodides
Transformations
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Zusammenfassung:Deselenylation reaction of [beta]-chloro- and [beta]-oxyselenides proceeded efficiently by treatment with tetrabutylammonium iodide (TBAI) to afford alkenes in good yields. It was established that selenenyl iodides were formed in these reactions. Catalytic transformation of [beta]-chloro- and [beta]-oxyselenides to alkenes was also developed.
ISSN:0366-7022
1348-0715