Superparamagnetic nanotraps containing MIP based mimic lipase for biotransformations uses

The nanoparticle comprises a superparamagnetic iron oxide nanoparticle core conjugated with trimethoxylsilyl propylmethacrylate (TMSPM) and methacryloylamido serine (MASE), methacryloylamido histidine (MAH), methacryloylamido glutamic acid (MAGA) monomers, and p -nitrophenyl palmitate ( p -NPP) whic...

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Veröffentlicht in:Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology 2011-05, Vol.13 (5), p.2073-2079
Hauptverfasser: Keçili, Rüstem, Özcan, Ayça Atılır, Ersöz, Arzu, Hür, Deniz, Denizli, Adil, Say, Rıdvan
Format: Artikel
Sprache:eng
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Zusammenfassung:The nanoparticle comprises a superparamagnetic iron oxide nanoparticle core conjugated with trimethoxylsilyl propylmethacrylate (TMSPM) and methacryloylamido serine (MASE), methacryloylamido histidine (MAH), methacryloylamido glutamic acid (MAGA) monomers, and p -nitrophenyl palmitate ( p -NPP) which is a substrate of lipase as a template molecule, which enables the creation of lipase active region. The resulting hybrid superparamagnetic nanotraps are magnetically separable, highly active, and stable under harsh conditions. In this study, the advantages of high selectivity of molecular imprinting technique have used to get mimic lipase for the synthesis of methyl jasmonate and methyl oleate.
ISSN:1388-0764
1572-896X
DOI:10.1007/s11051-010-9962-x