Synthesis of nanosized mesoporous silicon by magnesium-thermal method used as anode material for lithium ion battery

Magnesium thermal reduction of the silica aggregation following with HF etching is used to obtain mesoporous nano-Silicon. The product shows an 1844 mAh g super(-1) discharge capacity in the first cycle with 400 mA g super(-1) current density and it still delivers a 1444 mAh g super(-1) capacity aft...

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Veröffentlicht in:Journal of power sources 2014-09, Vol.262, p.10-14
Hauptverfasser: HAI ZHONG, HUI ZHAN, ZHOU, Yun-Hong
Format: Artikel
Sprache:eng
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Zusammenfassung:Magnesium thermal reduction of the silica aggregation following with HF etching is used to obtain mesoporous nano-Silicon. The product shows an 1844 mAh g super(-1) discharge capacity in the first cycle with 400 mA g super(-1) current density and it still delivers a 1444 mAh g super(-1) capacity after 100 cycles. Additionally, it presents a good rate capability. The mesoporous morphology and the ultra-fine particle are the reasons of the good electrochemical property.
ISSN:0378-7753
1873-2755
DOI:10.1016/j.jpowsour.2014.03.108