Impact of environmental conditions on the sorption behavior of Pb(II) onto attapulgite

This paper examined the application of attapulgite as an adsorbent for the removal of Pb(II) from heavy metal-contaminated water under various conditions. The sorption results indicated that the sorption of Pb(II) on attapulgite was strongly dependent on ionic strength at pH  10.0 was mainly dominat...

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Veröffentlicht in:Journal of radioanalytical and nuclear chemistry 2013-02, Vol.295 (2), p.1589-1596
Hauptverfasser: Chi, Yaling, Chen, Yuantao, Liu, Xia, Guo, Zhijun, Xiao, Jiang, Xu, Jiangbo, Zhao, Wenhua
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Sprache:eng
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Zusammenfassung:This paper examined the application of attapulgite as an adsorbent for the removal of Pb(II) from heavy metal-contaminated water under various conditions. The sorption results indicated that the sorption of Pb(II) on attapulgite was strongly dependent on ionic strength at pH  10.0 was mainly dominated by inner-sphere surface complexation. The sorption of Pb(II) on attapulgite was affected by foreign ions in solution at pH  7.0. The thermodynamic parameters (Δ H °, Δ S ° and Δ G °) were evaluated from the temperature-dependent sorption isotherms, and the results indicated that the sorption process of Pb(II) on attapulgite was spontaneous and endothermic in nature.
ISSN:0236-5731
1588-2780
DOI:10.1007/s10967-012-2324-7