Effect of Nanoalumina on the Tribology Performance of C4-Ether-Linked Bismaleimide-Toughened Epoxy Nanocomposites

In the present investigation, C4-ether-linked bismaleimide-toughened epoxy-reinforced alumina nanocomposites were formulated. The silane-functionalized nanoparticles are covalently connected to the matrix through the reaction between epoxide groups during curing, and as a consequence, the interfacia...

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Veröffentlicht in:Tribology letters 2014-04, Vol.54 (1), p.67-79
Hauptverfasser: Mandhakini, M., Lakshmikandhan, T., Chandramohan, A., Alagar, Muthukaruppan
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Sprache:eng
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Zusammenfassung:In the present investigation, C4-ether-linked bismaleimide-toughened epoxy-reinforced alumina nanocomposites were formulated. The silane-functionalized nanoparticles are covalently connected to the matrix through the reaction between epoxide groups during curing, and as a consequence, the interfacial interaction between the alumina nanoparticle and matrix was enhanced. The T g increased with the addition of alumina nanoparticles up to 5 wt% beyond which the T g decreased due to phase segregation. The nanoindentation studies revealed that the hardness and the elastic modulus of the nanocomposites had increased with the filler concentration up to 5 wt% beyond which it showed a decreasing trend. The wear performance of the hybrid nanocomposite was significantly lower than those of the epoxy nanocomposite. The nanocomposites with 5 wt% Al 2 O 3 showed greatest improvement in wear resistance compared to higher alumina concentration, and the key factor riding the wear resistance is due to positive rolling effect phenomenon.
ISSN:1023-8883
1573-2711
DOI:10.1007/s11249-014-0309-0