Palladium-catalyzed esterification of aryl halides using aryl formates without the use of external carbon monoxide

Aryl formates are efficient carbon monoxide sources in palladium-catalyzed esterification of aryl halides. The carbonylation readily proceeds at ambient pressure without the use of external carbon monoxide to afford the corresponding esters in high yields.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2012-08, Vol.48 (64), p.8012-8014
Hauptverfasser:	Fujihara, Tetsuaki, Hosoki, Tomoya, Katafuchi, Yuko, Iwai, Tomohiro, Terao, Jun, Tsuji, Yasushi
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Carbon monoxide Carbon Monoxide - chemistry Carbonyls Catalysis Esterification Esters Esters - chemical synthesis Esters - chemistry External pressure Formates Formates - chemistry Halides Hydrocarbons, Halogenated - chemistry Molecular Structure Organometallic Compounds - chemistry Palladium - chemistry
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Beschreibung
Zusammenfassung:	Aryl formates are efficient carbon monoxide sources in palladium-catalyzed esterification of aryl halides. The carbonylation readily proceeds at ambient pressure without the use of external carbon monoxide to afford the corresponding esters in high yields.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c2cc33944g