Linear trinuclear Zn(II)-Ce(III)-Zn(II) complex which behaves as a single-molecule magnet

Linear trinuclear Zn(II)-Ce(III)-Zn(II) complex which behaves as a single-molecule magnet

Linear Zn(II)-Ce(III)-Zn(II) complex, which involves only one 4f electron as a spin source, behaves as an SMM. Easy-axis magnetic anisotropy for the ground (2)F(5/2) state of Ce(III) was achieved by a uni-axial crystal field, which is formed with four phenoxo oxygens as axial donors with the other f...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2013-02, Vol.42 (8), p.2683-2686
Hauptverfasser: Hino, Shiori, Maeda, Moe, Yamashita, Kei, Kataoka, Yumiko, Nakano, Motohiro, Yamamura, Tomoo, Nojiri, Hiroyuki, Kofu, Maiko, Yamamuro, Osamu, Kajiwara, Takashi
Format: Artikel
Sprache:eng
Schlagworte:
Crystals
Grounds
Magnetic anisotropy
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Zusammenfassung:Linear Zn(II)-Ce(III)-Zn(II) complex, which involves only one 4f electron as a spin source, behaves as an SMM. Easy-axis magnetic anisotropy for the ground (2)F(5/2) state of Ce(III) was achieved by a uni-axial crystal field, which is formed with four phenoxo oxygens as axial donors with the other five oxygens as equatorial donors.
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt32812g