Synthesis, structure characterization, and thermochemistry of the coordination compounds of pyridine-2,6-dicarboxylic acid with several metals (Ca and Co)

Two solid state complexes of pyridine-2,6-dicarboxylate with Ca 2+ and Co 2+ ions, Ca 2 (DPC) 2 (H 2 O) 6 (H 2 DPC) 2 (s) and Co(DPC) 2 ·Co(H 2 O) 5 ·2H 2 O(s), were synthesized. X-ray crystallography was applied to characterize the crystal structures of the two complexes. The molecular and cell stacking structures of the two complexes were shown; the crystal data and refinement details were summarized, and the selected bond lengths and angles of the title complexes were listed. Low-temperature heat capacities of the two complexes were measured with an automated adiabatic calorimeter in the temperature ranging from 78 to 380 K. Two polynomial equations of experimental molar heat capacities as a function of the temperature were obtained by the least-squares method. The smoothed molar heat capacities and thermodynamic functions of the complexes were calculated based on the fitted polynomial equations. In addition, thermodynamic properties of the two complexes were compared.