New approach to determine absolute partial pressures of ions in saturated vapors of inorganic materials

New approach to determine absolute partial pressures of ions in saturated vapors of inorganic materials

A new complex approach to determine absolute partial pressures of molecular and ionic components of vapor is advanced on the basis of a combination of mass-spectrometric and quantum-chemical methods using sodium bromide as an example. Thermodynamic parameters of molecules and ions and the electron w...

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Veröffentlicht in:Russian journal of inorganic chemistry 2011-08, Vol.56 (8), p.1312-1317
Hauptverfasser: Kudin, L. S., Ivanov, D. A., Butman, M. F., Dunaev, A. M.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Crystal structure
Inorganic Chemistry
Inorganic materials
Partial pressure
Physical Methods of Investigation
Quantum chemistry
Sodium bromides
Thermodynamics
Work functions
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Beschreibung
Zusammenfassung:A new complex approach to determine absolute partial pressures of molecular and ionic components of vapor is advanced on the basis of a combination of mass-spectrometric and quantum-chemical methods using sodium bromide as an example. Thermodynamic parameters of molecules and ions and the electron work function are determined for crystalline NaBr.
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023611080134