Ultra-thin hybrid polyhedral silsesquioxane–polyamide films with potentially unlimited 2D dimensions

Ultra-thin hybrid polyhedral silsesquioxane–polyamide films with potentially unlimited 2D dimensions

The formation of hybrid polyhedral silsesquioxane-polyamides, in the form of self-supporting or supported ultra-thin films, is presented. The thin films combine intrinsic local ordering of inorganic and organic constituents on the molecular scale with potentially infinite lateral macroscopic dimensi...

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Veröffentlicht in:Journal of materials chemistry 2012-01, Vol.22 (30), p.14835-14838
Hauptverfasser: Dalwani, Mayur, Zheng, Jumeng, Hempenius, Mark, Raaijmakers, Michiel J. T., Doherty, Cara M., Hill, Anita J., Wessling, Matthias, Benes, Nieck E.
Format: Artikel
Sprache:eng
Schlagworte:
Liquids
Materials selection
Order disorder
Penetration
Permeation
Selectivity
Thin films
Two dimensional
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Zusammenfassung:The formation of hybrid polyhedral silsesquioxane-polyamides, in the form of self-supporting or supported ultra-thin films, is presented. The thin films combine intrinsic local ordering of inorganic and organic constituents on the molecular scale with potentially infinite lateral macroscopic dimensions, are robust and flexible, and exhibit molecular selectivity in liquid permeation experiments.
ISSN:0959-9428
1364-5501
DOI:10.1039/c2jm31941a