Sequential synthesis of beta -amino alcohols using a CeO sub(2)-ZrO sub(2) bifunctional catalyst system

Sequential synthesis of beta -amino alcohols using a CeO sub(2)-ZrO sub(2) bifunctional catalyst system

CeO sub(2)-ZrO sub(2) was explored as a bifunctional catalyst system for the synthesis of beta -amino alcohols through epoxidation and subsequent aminolysis. Epoxidation of styrene to styrene oxide using t-butyl hydrogen peroxide (TBHP) as a green oxidant followed by subsequent aminolysis with diver...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Catalysis science & technology 2013-04, Vol.3 (5), p.1308-1313
Hauptverfasser: Parghi, Kalpesh D, Kale, Sandip R, Kahandal, Sandeep S, Gawande, Manoj B, Jayaram, Radha V
Format: Artikel
Sprache:eng
Schlagworte:
Alcohols
Amines
Catalysts
Epoxidation
Hydrogen peroxide
Oxides
Styrenes
Synthesis
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:CeO sub(2)-ZrO sub(2) was explored as a bifunctional catalyst system for the synthesis of beta -amino alcohols through epoxidation and subsequent aminolysis. Epoxidation of styrene to styrene oxide using t-butyl hydrogen peroxide (TBHP) as a green oxidant followed by subsequent aminolysis with diverse amines gave the corresponding beta -amino alcohols. CeO sub(2)-ZrO sub(2) was found to be a reusable and highly selective catalyst for both the epoxidation and aminolysis reactions.
ISSN:2044-4753
2044-4761
DOI:10.1039/c3cy20806k