Alteration of the course of the Michaelis–Arbuzov reaction in imidazolium ionic liquids

Room-temperature imidazolium ionic liquids [Rmim][X] (X = Br, BF 4, NTf 2) as a reaction medium change the reaction course of phosphorus(III) acid esters with primary alkyl halides, aryl bromides, and propargyl bromide to afford hydrophosphoryl compounds, products of oxidation of the starting phosph...

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Veröffentlicht in:Mendeleev communications 2010-05, Vol.20 (3), p.145-147
Hauptverfasser: Matveeva, Ekaterina V., Kozlov, Vladimir A., Odinets, Irina L.
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Odinets, Irina L.
description Room-temperature imidazolium ionic liquids [Rmim][X] (X = Br, BF 4, NTf 2) as a reaction medium change the reaction course of phosphorus(III) acid esters with primary alkyl halides, aryl bromides, and propargyl bromide to afford hydrophosphoryl compounds, products of oxidation of the starting phosphorus substrates, and 2,3-bis(phosphoryl)prop-1-enes, respectively.
doi_str_mv 10.1016/j.mencom.2010.05.007
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subjects Alterations
Aromatic compounds
Bromides
Esters
Halides
Ionic liquids
Oxidation
Phosphorus
title Alteration of the course of the Michaelis–Arbuzov reaction in imidazolium ionic liquids
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