Alteration of the course of the Michaelis–Arbuzov reaction in imidazolium ionic liquids

Alteration of the course of the Michaelis–Arbuzov reaction in imidazolium ionic liquids

Room-temperature imidazolium ionic liquids [Rmim][X] (X = Br, BF 4, NTf 2) as a reaction medium change the reaction course of phosphorus(III) acid esters with primary alkyl halides, aryl bromides, and propargyl bromide to afford hydrophosphoryl compounds, products of oxidation of the starting phosph...

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Veröffentlicht in:Mendeleev communications 2010-05, Vol.20 (3), p.145-147
Hauptverfasser: Matveeva, Ekaterina V., Kozlov, Vladimir A., Odinets, Irina L.
Format: Artikel
Sprache:eng
Schlagworte:
Alterations
Aromatic compounds
Bromides
Esters
Halides
Ionic liquids
Oxidation
Phosphorus
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Beschreibung
Zusammenfassung:Room-temperature imidazolium ionic liquids [Rmim][X] (X = Br, BF 4, NTf 2) as a reaction medium change the reaction course of phosphorus(III) acid esters with primary alkyl halides, aryl bromides, and propargyl bromide to afford hydrophosphoryl compounds, products of oxidation of the starting phosphorus substrates, and 2,3-bis(phosphoryl)prop-1-enes, respectively.
ISSN:0959-9436
DOI:10.1016/j.mencom.2010.05.007