Electrostatic heterocoagulation of carbon nanotubes and LiCoO sub(2) particles for a high-performance Li-ion cell

Nanotubes were coated on the surface of active LiCoO sub(2) particles using electrostatic heterocoagulation to enhance the electrochemical properties of a Li-ion battery. Only 0.5 wt% of multiwalled carbon nanotubes (MWCNTs) was added as a conducting agent into the LiCoO sub(2) cathode, which had a density of 4.0 g cm super(-3). We found that our electrode that was prepared using heterocoagulation with 0.5 wt% of thin MWCNTs maintained a volumetric capacitance of 403 mAh cm super(-1) after 40 cycles from the initial 624 mAh cm super(-1), compared with previous result of 310 mAh cm super(-1) obtained from simple mixing with 3 wt% MWCNTs. The high volumetric capacity with smaller swelling using less amount of MWCNTs was attributed to the self-assembled nanotube network formed between active particles during coagulation, which was maintained with volume expansion during cycle testing.