Highly active Cu/MgO catalysts for selective dehydrogenation of benzyl alcohol into benzaldehyde using neither O sub(2) nor H sub(2) acceptor
Aiming at developing an efficient catalyst for selective dehydrogenation of benzyl alcohol into benzaldehyde in the absence of O sub(2) and H sub(2) acceptor, a series of Cu/MgO catalysts with Cu loading of 1, 3, 5, and 7% have been prepared, of which the 5% Cu/MgO catalyst in the gas phase exhibite...
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Veröffentlicht in: | Catalysis science & technology 2012-08, Vol.2 (9), p.1833-1838 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Aiming at developing an efficient catalyst for selective dehydrogenation of benzyl alcohol into benzaldehyde in the absence of O sub(2) and H sub(2) acceptor, a series of Cu/MgO catalysts with Cu loading of 1, 3, 5, and 7% have been prepared, of which the 5% Cu/MgO catalyst in the gas phase exhibited a remarkable performance with 98% conversion and 97% selectivity and in support of the performance, the catalysts have been characterized by different techniques like BET surface area analysis, XRD, TEM, CO sub(2)-TPD, N sub(2)O pulse chemisorption, XPS and TPR. |
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ISSN: | 2044-4753 2044-4761 |
DOI: | 10.1039/c2cy20222k |