Highly active Cu/MgO catalysts for selective dehydrogenation of benzyl alcohol into benzaldehyde using neither O sub(2) nor H sub(2) acceptor

Aiming at developing an efficient catalyst for selective dehydrogenation of benzyl alcohol into benzaldehyde in the absence of O sub(2) and H sub(2) acceptor, a series of Cu/MgO catalysts with Cu loading of 1, 3, 5, and 7% have been prepared, of which the 5% Cu/MgO catalyst in the gas phase exhibite...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Catalysis science & technology 2012-08, Vol.2 (9), p.1833-1838
Hauptverfasser: Marella, Ravi Kumar, Prasad Neeli, Chinna Krishna, Rao Kamaraju, Seetha Rama, Burri, David Raju
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Aiming at developing an efficient catalyst for selective dehydrogenation of benzyl alcohol into benzaldehyde in the absence of O sub(2) and H sub(2) acceptor, a series of Cu/MgO catalysts with Cu loading of 1, 3, 5, and 7% have been prepared, of which the 5% Cu/MgO catalyst in the gas phase exhibited a remarkable performance with 98% conversion and 97% selectivity and in support of the performance, the catalysts have been characterized by different techniques like BET surface area analysis, XRD, TEM, CO sub(2)-TPD, N sub(2)O pulse chemisorption, XPS and TPR.
ISSN:2044-4753
2044-4761
DOI:10.1039/c2cy20222k