super(1)H and super(27)Al NMR Study of Li[AlH sub(4)] + Ti Compounds in Solution

super(1)H and super(27)Al NMR Study of Li[AlH sub(4)] + Ti Compounds in Solution

A broad sextet signal in the super(1)H NMR spectrum of Li[AlH sub(4)] in THF-d sub(8), centered at 2.75 ppm with J/Hz = 176, was assigned to the signal from [AlH sub(4)] super(-). Also investigated were the reactions of Li[AlH sub(4)] with TiCl sub(3) or Ti(OBu) sub(4) in THF.

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Veröffentlicht in:Bulletin of the Chemical Society of Japan 2009-01, Vol.82 (6), p.709-711
Hauptverfasser: Takeuchi, Shou, Senoh, Hiroshi, Zhang, Shu, Takeshita, Hiroyuki T, Kiyobayashi, Tetsu, Xu, Qiang, Kuriyama, Nobuhiro
Format: Artikel
Sprache:eng
Schlagworte:
Nuclear magnetic resonance
Titanium
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Zusammenfassung:A broad sextet signal in the super(1)H NMR spectrum of Li[AlH sub(4)] in THF-d sub(8), centered at 2.75 ppm with J/Hz = 176, was assigned to the signal from [AlH sub(4)] super(-). Also investigated were the reactions of Li[AlH sub(4)] with TiCl sub(3) or Ti(OBu) sub(4) in THF.
ISSN:1348-0634
DOI:10.1246/bcsj.82.709