Simplified Tandem Polymer Solar Cells with an Ideal Self-Organized Recombination Layer

A new tandem architecture for printable photovoltaics using a versatile organic nanocomposite containing photoactive and interfacial materials is demonstrated. The nanocomposite forms an ideal self‐organized recombination layer via a spontaneous vertical phase separation, which yields a simplified tandem structure fabricated with only four component layers and a high tandem efficiency of 10.8%.