Ionic conductivity of YSZ/CZO multilayers with variable lattice mismatch

Heterostructured multilayers have been controversially reported to alter the oxygen ion conductivity of solid electrolytes by inducing interfacial mechanical strain. Here, we fabricated thin film multilayers composed of 9 mol% Y 2 O 3 doped ZrO 2 (YSZ) and Ce 1− x Zr x O 2 (CZO) to systematically qu...

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Veröffentlicht in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2015-01, Vol.3 (5), p.2378-2386
Hauptverfasser: Shen, Weida, Hertz, Joshua L
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Sprache:eng
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Zusammenfassung:Heterostructured multilayers have been controversially reported to alter the oxygen ion conductivity of solid electrolytes by inducing interfacial mechanical strain. Here, we fabricated thin film multilayers composed of 9 mol% Y 2 O 3 doped ZrO 2 (YSZ) and Ce 1− x Zr x O 2 (CZO) to systematically quantify the effects of tensile strain on the oxygen-ion conduction behavior in YSZ. A significant advantage of using CZO is that its lattice parameter can be continuously varied by adjusting the Ce/Zr atomic ratio, simplifying the strain control over the neighboring YSZ layers. Three different sets of multilayers composed of YSZ with CeO 2 , or with Ce 0.70 Zr 0.30 O 2 (CZO30), or with Ce 0.55 Zr 0.45 O 2 (CZO45) were prepared on Al 2 O 3 substrates with interfacial lattice mismatch of +5.2%, +3.7%, and +2.9%, respectively. When decreasing the individual layer thicknesses from 35 nm to 5 nm, all of the multilayers exhibited little change of the conductivity, with values consistently near that of bulk YSZ. X-ray diffraction results indicate that the interfacial strains were largely relaxed. Suggestions that multilayers are unable to effect ionic conductivity changes must therefore consider the difficulties in obtaining lattice mismatch-based elastic strain, even at
ISSN:2050-7488
2050-7496
DOI:10.1039/c4ta03892d