Structural factors of interaction of crown ethers with aerosil surface

An attempt to consider the effect of the structure and composition of benzo-, dibenzo-, and aliphatic crown ethers (more than 40 compounds) on the characteristics of their interaction with surface groups of A-300 aerosil is carried out by comparing the Henry (K H ) and Langmuir (K L ) constants and...

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Veröffentlicht in:	Protection of metals and physical chemistry of surfaces 2015, Vol.51 (1), p.93-105
Hauptverfasser:	Voloshina, N. S., Ognichenko, L. N., Kuz’min, V. E., Pluzhnik-Gladyr, S. M., Kamalov, G. L.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aliphatic compounds Characterization and Evaluation of Materials Chemistry and Materials Science Composition effects Constants Corrosion and Coatings Crown ethers Formations Fragments Industrial Chemistry/Chemical Engineering Inorganic Chemistry Materials Science Metallic Materials Molecular and Supramolecular Structures at the Interfaces Physical chemistry Tribology
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Beschreibung
Zusammenfassung:	An attempt to consider the effect of the structure and composition of benzo-, dibenzo-, and aliphatic crown ethers (more than 40 compounds) on the characteristics of their interaction with surface groups of A-300 aerosil is carried out by comparing the Henry (K H ) and Langmuir (K L ) constants and analyzing the main factors and structural fragments that facilitate or hamper the formation of corresponding surface compounds by quantitative-structure-property-relationships method.
ISSN:	2070-2051 2070-206X
DOI:	10.1134/S2070205114050190