Oxidative Povarov Reaction via sp3 C–H Oxidation of N‑Benzylanilines Induced by Catalytic Radical Cation Salt: Synthesis of 2,4-Diarylquinoline Derivatives

Oxidative Povarov Reaction via sp3 C–H Oxidation of N‑Benzylanilines Induced by Catalytic Radical Cation Salt: Synthesis of 2,4-Diarylquinoline Derivatives

Oxidative Povarov reaction of N-benzylanilines was realized under catalytic radical cation salt induced conditions. The mechanism studies revealed that a radical intermediate was involved in this catalytic oxidation. This method provides a new way to synthesize 2,4-diarylquinoline derivatives.

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Veröffentlicht in:Organic letters 2015-03, Vol.17 (6), p.1409-1412
Hauptverfasser: Liu, Jing, Liu, Fang, Zhu, Yingzu, Ma, Xingge, Jia, Xiaodong
Format: Artikel
Sprache:eng
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Zusammenfassung:Oxidative Povarov reaction of N-benzylanilines was realized under catalytic radical cation salt induced conditions. The mechanism studies revealed that a radical intermediate was involved in this catalytic oxidation. This method provides a new way to synthesize 2,4-diarylquinoline derivatives.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.5b00244