A Flux-Gradient System for Simultaneous Measurement of the CH sub( 4), CO sub( 2), and H sub( 2)O Fluxes at a Lake-Air Interface

Inland lakes play important roles in water and greenhouse gas cycling in the environment. This study aims to test the performance of a flux-gradient system for simultaneous measurement of the fluxes of water vapor, CO2, and CH4 at a lake-air interface. The concentration gradients over the water surface were measured with an analyzer based on the wavelength-scanned cavity ring-down spectroscopy technology, and the eddy diffusivity was measured with a sonic anemometer. Results of a zero-gradient test indicate a flux measurement precision of 4.8 W m-2 for water vapor, 0.010 mg m... s... for CO2, and 0.029 ...g m... s... for CH4. During the 620 day measurement period, 97%, 69%, and 67% of H2O, CO2, and CH4 hourly fluxes were higher in magnitude than the measurement precision, which confirms that the flux-gradient system had adequate precision for the measurement of the lake-air exchanges. This study illustrates four strengths of the flux-gradient method: (1) the ability to simultaneously measure the flux of H2O, CO2, and CH4; (2) negligibly small density corrections; (3) the ability to resolve small CH4 gradient and flux; and (4) continuous and noninvasive operation. The annual mean CH4 flux (1.8 g CH4 m... year...) at this hypereutrophic lake was close to the median value for inland lakes in the world (1.6 g CH4 m... year...). The system has adequate precision for CH4 flux for broad applications but requires further improvement to resolve small CO2 flux in many lakes. (ProQuest: ... denotes formulae/symbols omitted.)