A fast and effective method for N-doping TiO2 by post treatment with liquid ammonia: visible light photocatalysis

TiO2 thin films prepared by sol–gel synthesis were N-doped by post treating with liquid ammonia and annealing at 500 °C. Characterisation by X-ray diffraction and Raman spectroscopy confirmed that the anatase crystal type was retained and present in all samples. Scanning electron microscopy showed that treatment with liquid ammonia had no significant effect on the film morphology. Functional testing under filtered while light conditions involving water contact angle, and the photo destruction of both Resazurin and Stearic acid showed the ammonia treated samples to be active visible light photocatalysts in contrast to the pure TiO2 and the blank controls. X-ray Photoelectron Spectroscopy studies indicate the presence of interstitial nitrogen (N1s=400eV) suggesting that the origin of the enhanced photocatalytic activity is most likely due to oxygen vacancies created by the interstitial nitrogen incorporation. This synthesis method utilises a simple, inexpensive and highly effective post treatment route to N-dope TiO2 and produces visible light photocatalysts with potential applications in self-cleaning and healthcare environments. •Synthesis and characterisation of N-doped TiO2 thin films•N-doping by a post treatment with liquid ammonia•Enhanced photocatalytic activity•Easy enhancement of current TiO2 based technologies