Corrosion behaviour of 316L stainless steel and anti-corrosion materials in a high acidified chloride solution

•Severe general corrosion accompanied by localized pitting occurred on 316L SS surface in a high acidified chloride solution.•Surface roughness, surface potential difference and the electrochemical non-homogeneity of 316L SS in the test solution were investigated.•TA2, type 2507 SS and type 254SMo SS exhibit good corrosion resistance in the test solution. The corrosion behaviour of a type 316L (UNS S31603) stainless steel (SS) expansion joint in a simulated leaching solution of sediment on blast furnace gas pipeline in a power plant is investigated by using dynamic potential polarization curves, electrochemical impedance spectroscopy (EIS), optical microscope, atomic force microscope (AFM) and Scan Kelvin Probe (SKP). Severe general corrosion accompanied by pitting corrosion occurs on the type 316L SS surface in this solution. As the immersion period increases, the charge transfer resistance Rct decreases, the dissolution rate accelerates, the surface roughness increases and the surface potential difference enhances significantly. Then eight corrosion-resistant materials are tested, the corrosion rates of type 254SMo SS, type 2507 SS and TA2 are relatively minor in the solution. The corrosion resistance properties of TA2 is most excellent, indicating it would be the superior material choice for blast furnace gas pipeline.