Synthesis of new copper( i ) based linear 1-D-coordination polymers with neutral imidazolinium-dithiocarboxylate ligands

Synthesis of new copper( i ) based linear 1-D-coordination polymers with neutral imidazolinium-dithiocarboxylate ligands

An imidazolinium-dithiocarboxylate betaine has been applied for the first time as a ligand in a coordination polymer with copper( i ) halides. The resulting 1-D-coordination compounds show a linear double chain structure with trigonally coordinated copper( i ). The potential of the material as a het...

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Veröffentlicht in:RSC advances 2015, Vol.5 (12), p.9217-9220
Hauptverfasser: Neuba, A., Ortmeyer, J., Konieczna, D. D., Weigel, G., Flörke, U., Henkel, G., Wilhelm, R.
Format: Artikel
Sprache:eng
Schlagworte:
Betaines
CATALYSTS
Chains (polymeric)
Coordination polymers
FABRICATION
Halides
LIGANDS
Photocatalysis
POLYMERS
Synthesis
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Beschreibung
Zusammenfassung:An imidazolinium-dithiocarboxylate betaine has been applied for the first time as a ligand in a coordination polymer with copper( i ) halides. The resulting 1-D-coordination compounds show a linear double chain structure with trigonally coordinated copper( i ). The potential of the material as a heterogeneous photocatalyst was explored.
ISSN:2046-2069
2046-2069
DOI:10.1039/C4RA09033K