A photochromic naphthalene diimide coordination network sensitized by polyoxometalates

A photochromic naphthalene diimide coordination network sensitized by polyoxometalates

Metal-ion-directed assembly of naphthalene diimide tectons cooperatively enhanced by anion-π interactions of giant anions, PMo12O40(3-), leads to a novel organic-inorganic hybrid with ultrafast-responsive photochromic properties, which is attributed to the polyoxometalate-sensitized photo-induced ra...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2014-12, Vol.43 (48), p.17908-17911
Hauptverfasser: Liu, Jian-Jun, Wang, Yao, Hong, Yu-Jian, Lin, Mei-Jin, Huang, Chang-Cang, Dai, Wen-Xin
Format: Artikel
Sprache:eng
Schlagworte:
Anions
Assembly
Diimide
Lead (metal)
Naphthalene
Networks
Radicals
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Zusammenfassung:Metal-ion-directed assembly of naphthalene diimide tectons cooperatively enhanced by anion-π interactions of giant anions, PMo12O40(3-), leads to a novel organic-inorganic hybrid with ultrafast-responsive photochromic properties, which is attributed to the polyoxometalate-sensitized photo-induced radical generation of naphthalene diimide units.
ISSN:1477-9226
1477-9234
DOI:10.1039/c4dt02641a